There are plenty of tools out there in JS to lighten, darken, and blend colors. There are also plenty of color combination pickers; I’m sure we can build something useful if we choose. But it’s not so clear how much our existing themes would match something derivable this way based on a small collection of well-chosen colors. There are 135 named color keys in Vanilla!
This would be a useful place for TW6 to break backward compatibility, and move to such a model. Whether it’s Captivate’s three colors or four or five, or even six, it would be great to simply move in this direction. Trying to do it now in a backwardly compatible way is going to be tricky though.